LUMINOUS GLAZING WITH OPTICAL ISOLATOR

专利摘要:
The present invention relates to a luminous glazing unit (100) comprising: a first glass substrate (1) made of mineral glass and in optical contact with the first glass substrate: a polymeric layer chosen from a lamination interlayer (7); associated with a tinted and / or reflective element (1 '), and / or an opaque polymeric encapsulation, - a porous silica layer (2), - a light source (4), optically coupled to the first glass substrate, - light extraction means (6) associated with the guide glass; - a protective coating (3), mineral and transparent, directly on the porous silica layer and directly under the polymeric layer.
公开号:FR3015926A1
申请号:FR1363762
申请日:2013-12-31
公开日:2015-07-03
发明作者:Matthieu Berard；Brice Dubost；Stephanie Morlens；Mauricette Rondet
申请人:Saint Gobain Glass France SAS；Compagnie de Saint Gobain SA；
IPC主号:

专利说明:

[0001] The present invention relates to the field of lighting and more particularly relates to a light glazing with optical isolator. It is known to form a luminous glazing by illuminating a glass by the edge with LEDs. The light thus injected is guided by total internal reflection inside this glass thanks to the index contrast with the surrounding materials. This light is then extracted using scattering patterns.
[0002] Document W02008 / 059170 proposes in connection with FIG. 11, a lighting roof 1 "with illumination by the wafer comprising: a first glass, of optical index n1 equal to about 1.5, for example a clear or extraclear glass, a tinted glass in the mass, a lamination interlayer, between the first and second glasses, for example a polyvinyl butyral, a discontinuous porous silica gel sol layer forming an optical separator, deposited on the first glass, the layer being optical index n2 equal to 1.1 and thickness 400nm, - a source of illumination by the edge of the first substrate, in the form of light-emitting diodes preferably housed in a groove of the first glass 1, - an internal backscattering network between the porous layer and the first substrate, in the form of patterns of dimensions adapted to the desired illumination.However, this solution is not robust enough or at least its effectiveness is not optimal, it is wishes to better control the extraction of light at one or well defined points for example well distributed on the surface of the glass. To overcome these drawbacks, the invention proposes as a first object a luminous glazing comprising: a first glass substrate, made of mineral glass (transparent, clear, extraclear), of refractive index n1 of less than 1.6 at 550 nm, better in the entire visible spectrum, and even less than 1.55 or even 1.5, with first and second main faces and a wafer, and in optical contact with the first glass substrate: a polymeric layer, optical contact with the first glass substrate, chosen from at least one of the following elements: a laminating interlayer of thermoplastic material associated with a tinted and / or diffusing and / or reflecting element (mirror, spy mirror) and / or an opaque polymeric encapsulation or a polymeric encapsulation primer, in particular opaque, under an opaque polymeric encapsulation, an optical isolator, on the first glass substrate (especially directly, at least without z one (s) with light extraction means) and under the polymeric layer, the insulator comprising (better is constituted) a porous silica layer of thickness e2 of at least 400 nm and preferably at most 1, 51..tm, better still at least 600 nm, of refractive index n2 at 550 nm (better in the visible spectrum as a whole) of at most 1.35, preferably at most 1.25 and even lower at 1.2 - a light source (visible), preferably a set of light-emitting diodes (aligned) or an extracting optical fiber, optically coupled to the first glass substrate, preferably by the wafer, called the coupling wafer, or alternatively optically coupled to one of the main faces (in particular with a hole for accommodating diodes), the first glass substrate, said guiding glass guiding the light emitted by the light source, - light extraction means (resulting from the guiding ) associated with the guide glass - in particular diffusing means on the side the first main face and / or the side of (even preferably on) the second main face and / or in the mass of the guide glass - light extraction means possibly forming a concentrator of the light.
[0003] The possible polymeric encapsulation and primary encapsulation is also preferably opposite the wafer, in particular without hindering said optical coupling (in particular further from the coupling wafer than the light source). The luminous glazing further comprises a protective coating, mineral and transparent, directly on the porous silica layer and directly under the polymeric layer.
[0004] Here is the guide glass which is coated with the optical isolator. The lamination interlayer may be tinted and / or laminated with a second tinted glass substrate, of mineral or organic glass and / or carrier of a tinted film on the interlayer lamination side or main face opposite the lamination. The laminating interlayer can be laminated with a second glass substrate made of mineral or organic glass, the second substrate with a so-called principal surface bonded to the lamination interlayer, bonding face coated with a decorative layer and / or masking in particular an enamel and / or a paint (lacquer) or a reflective layer, peripheral and optical coupling side (frame), or distributed and even substantially covering the bonding face. Under the paint (lacquer), there may be a transparent adhesion primer preferably. Alternatively one can have: the following sequence: guide glass / optical isolator / protective coating / laminating interlayer (PVB) with paint or ink decor (/ second glass substrate (transparent, tinted)), the following sequence: guide glass / optical isolator / protective coating / laminating interlayer / decorative element (film with decorative paint etc) / other laminating interlayer (transparent, tinted) / second glass substrate (transparent, tinted). A laminated glazing with a possible primary undercoat adhesion is described in WO2009 / 081077. In order to optimize the adhesion between the paint and a possible interlay sheet of polymeric lamination, the paint is preferably subjected to the action of a plasma, in particular by a treatment of the corona discharge type, before heat treatment. For the same purpose, it is also possible to deposit on the paint silanes, for example by spraying or scouring. These treatments make it possible to use paints, especially lacquers, whose adhesion with the polymer interlayer sheets is naturally weak. They nevertheless generate an additional cost and are therefore not preferred. The lamination interlayer may be laminated with a second glass substrate made of mineral or organic glass, the second substrate with a so-called principal surface bonded to the lamination interlayer, the bonding face or the opposite face comprises a diffusing layer (deposit , in particular reported plastic element in particular glued with an optical adhesive) and / or said second substrate is diffusing and / or a diffusing element is between the protective coating and the interlayer lamination.
[0005] We can have: - the following sequence: guide glass / optical isolator / protective coating / laminating interlayer (PVB) with paint or diffusing ink / second glass substrate (transparent or tinted), - or the following sequence: glass guide / optical isolator / protective coating / lamination interlayer / diffusing element (film with paint etc) / other lamination interlayer / second glass substrate (transparent or tinted).
[0006] A diffusing element is conventionally a surface texturing of height between 100 nm and 100 μm, preferably micrometric, or a matrix with diffusing particles. It may alternatively be a liquid crystal system as described later. If the guide glass is laminated via the spacer, its main face connected to the spacer is said inner face and the opposite main face said outer face. Another object of the invention is a luminous glazing comprising: a glass substrate, made of inorganic (transparent, clear, extraclear) or organic glass, having a refractive index n1 of less than 1.6 at 550 nm, better in the whole of visible spectrum, with main faces and a wafer, laminated by a main face, said connecting face to another glass substrate, via a laminating interlayer made of thermoplastic material (transparent, clear, extraclear, diffusing part of the extraction means) the other glass substrate, made of mineral glass with a first main face, called the laminating face, second tinted and / or diffusing glass substrate and / or carrier of a tinted and / or diffusing and / or reflective element on the main face; opposed to the lamination face, an optical isolator directly on the lamination face in particular directly, at least outside the zone (s) with light extraction means) and under the interlayer, the isolator com carrying (better being constituted by) a porous silica layer of thickness e2 of at least 400 nm and preferably at most 1.511m, better still at least 600 nm, of refractive index n2 at 550 nm (better in the entire visible spectrum) of at most 1.35, preferably at most 1.25 and even less than 1.2, the other glass substrate being called an isolated substrate, a (visible) light source, preferably a set of electroluminescent diodes (aligned) or an extracting optical fiber, optically coupled to the first glass substrate, preferably by the wafer, called the coupling wafer, or alternatively optically coupled to one of the main faces (especially with a hole for accommodating diodes), the first glass substrate, said guide substrate, guiding the light emitted by the source, light extraction means (resulting from the guide) associated with the guiding substrate - in particular diffusing means of the laminating side and / or the opposite side (even preferably on the so-called outer face) and / or in the mass of the guiding substrate - light extraction means possibly forming a concentrator of the light. This luminous glazing further comprises a protective coating, mineral and transparent, directly on the porous silica layer and directly under the lamination interlayer. Here, it is the separate insulated substrate of the guide substrate which is coated with the optical isolator. This luminous glazing can also comprise, if the guide substrate is mineral on the main face, said outer face, opposite the connecting face, peripherally: another optical isolator directly on the lamination face, the insulator comprising a layer of porous silica with a thickness e2 of at least 400 nm and preferably at most 1.5 μm, better still at least 600 nm, of refractive index n2 at 550 nm (better in the whole of the visible spectrum) of plus 1.35, preferably not more than 1.25 and even less than 1.2, the other glass substrate being called isolated substrate, preferably identical to said optical isolator, another protective coating, mineral and transparent, directly on the porous silica layer, preferably identical to said protective coating (nature or even thickness) an opaque polymeric encapsulation or a polymeric encapsulation primer, in particular opaque, under an opaque polymeric encapsulation, in p riphérie and preferably facing the edge of the guide substrate. The Applicant has found that by directly applying the lamination interlayer to the porous silica layer (on the guide glass or the insulated substrate) its optical isolator function was lost.
[0007] It is likely that pores, especially those open at the surface, of the porous layer are polluted at the time of manufacture and that pollutants remain trapped in the pores even after heat treatment (for lamination).
[0008] The Applicant has also found that by directly applying a polymeric encapsulation primer or a polymeric encapsulation on the porous silica layer its function of optical isolator was decreased.
[0009] In the absence of optical isolator, the optical losses are particularly significant when a tinted element has an IL less than 85% especially for a thickness (reference) of 4mm or even 2mm. It is measured conventionally according to the EN410 standard with illuminant D65 and a spectrophotometer. Even a reflecting element, especially a specular element, in particular a mirror, a silver mirror or a spy mirror, can advantageously be optically isolated for better guidance. Examples of spy mirror layers are described in WO2012 / 035258. The protective coating preferably covers the entire surface of the porous silica layer for simplicity even where appropriate in one or more areas without the organic layer. The first glass substrate assembly (guide glass), porous silica layer and protective coating may have an IL light transmission of at least 80% and even at least 90% especially for a glass thickness (reference) 4mm or even 2mm.
[0010] The transparency of the protective coating makes it possible in particular to preserve the vision through the luminous glazing or even the tint conferred by the tinted element. The transparency of the protective coating makes it possible in particular to preserve the vision of a decorative element, for example a paint (in particular a lacquer) in particular on the second glass substrate or the insulated substrate (and / or an enamel on the second substrate glassmaker or the insulated substrate, enamel or paint (lacquer) distributed on a surface of the second glass substrate (bonding face or opposite face) or of the insulated substrate (opposite face to face of lamination), substantially covering this surface or in discrete patterns or still in edge (lateral and / or longitudinal bands, frame) Transparency is here taken in the broad sense, implying a vision through, the protective coating may be colorless or tinted, neutral color or bright color. even be adjusted according to the tint of the dyed element, in particular second glass substrate or the insulated substrate and / or the lamination interlayer itself integrated for a complement of color, in the realization with the guiding glass. The protective coating may for example be adjusted depending on the color of the paint and / or enamel used for decorative purposes, for additional color.
[0011] The paint or enamel is generally opaque but may alternatively allow more light to pass, for example applied in a thin layer and / or by adjusting the level of charges in the binder.
[0012] The protective coating may be colored by nature (of the matrix) and / or for example by addition of coloring additives, may contain as a colloid of metal, metal oxide or metal salt. As sol-gel of colored silica, examples of the document WO2013 / 054041 can be cited. For simplicity, a protective coating may be preferred without additives or fillers, or more largely without (nano) particles. The transparency of the protective coating can allow to apply it directly in a given area (or more areas) on the bonding face or the lamination face if the optical isolator is discontinuous. Then, preferably, the protective coating is chosen to have a refractive index n3 of 550 nm (better in the visible spectrum as a whole) such that the difference n3-n1 is less than 0.1 better than at most 0.05. If the extraction means are above the lamination interlayer, further away from the guiding substrate, the lamination interlayer may preferably be of refractive index n3 at 550 nm (better in the whole visible spectrum) such that the gap at n-n-1 is less than 0.1 better than at most 0.05.
[0013] If the optical isolator is discontinuous and the extraction means are above the lamination interlayer, farther from the guide glass, the lamination interlayer may preferably be of refractive index n3 at 550 nm (Better in the visible spectrum as a whole) such that the gap at n-n-1 is less than 0.1 better than at most 0.05.
[0014] The outer face of the guide glass opposite to the inner face or the outer face opposite to the bonding face may be coated on the periphery of the polymeric encapsulation or the encapsulation primer and the polymeric encapsulation. In the case of the encapsulation primer and / or the encapsulation, the transparency of the protective coating is not essential however it may be desired to use the same coating as for the laminating interlayer in the case of a laminated glazing unit , to simplify. However, the luminous glazing with a polymeric encapsulation may be possibly monolithic (with a single inorganic glass, not laminated). However, in many applications the lamination is required, laminating with a preferably mineral glass substrate glass, for example for a laminated glass partition, a laminated glass door, a laminated vehicle glazing (roof, windshield and same side window).
[0015] Between the guide glass and a second glass substrate, said laminating interlayer may be: transparent, especially clear or extraclear, or diffusing (in volume rather than surface texturing) or carrying a diffusing layer, for example, an ink , a printed layer, for example local, and forming part or forming the extraction means if the optical isolator is discontinuous. The second glass substrate (flexible, rigid or semi-rigid) of mineral glass may be clear, extraclear or even diffusing or carrying a diffusing element (deposit, film attached) for example on the other side of its bonding face with the interlayer. Between the guiding substrate and the other glass substrate, said lamination interlayer may be: transparent, in particular preferably clear or extraclear, (optionally slightly tinted) or diffusing (in volume rather than surface texturing) or carrier a diffusing layer for example, an ink, a printed layer, for example local, and forming part or forming the extraction means. For automotive glazing, the second glass substrate, made of mineral glass, is tinted and even more preferably the lamination interlayer is tinted or the insulated substrate is tinted. The thickness of the glass substrate is preferably at most 3 mm. Table 1 below gives examples of glass sold by the Applicant. They are suitable for all windows of a vehicle, whether they are soaked or laminated. SGS THERMOCONTROL ® Absorbing / Venus glass improves thermal comfort by absorbing the energy load in the glass mass. These glasses are divided into two categories: "Vision" (Light Transmission> 70%) and "Privacy" (Light Transmission <70%). 35 Glass type TL (° / 0) TE (c) / 0) RE (c) / 0) SGS THERMOCONTROL® Venus Green 55 49 27 7 Green tinted high performance // Clear glass 28 16 3 SGS THERMOCONTROL® Venus Green 35 35 22 5 SGS THERMOCONTROL® Venus Gray 10 10 8 1 SGS THERMOCONTROL® Absorbing TSA3 + 71 44 18 Standard glass green 78 53 25 Table 1 Vision glass is suitable for all types of glazing in the vehicle: green / blue / gray and ensures reduced energy transmission (TE). The most popular color for this purpose is green. It was chosen because of its neutral appearance that does not affect the color harmony of a vehicle. The "Privacy" glass is a tinted glazing for thermal comfort and privacy. It is a dark green or dark gray stained glass. To ensure privacy, this glazing has light transmittance values that are below 70%, generally around 55% or less. Due to its dark hue, this type of glass also ensures low UV transmission (UV rays can cause skin irritation). In most countries, Venus / Privacy glass is suitable for rear side windows (after pillar B), rear window and roof. The only exception is the United States, where over-glazed glazing is prohibited on light-duty vehicles (except sunroof) and, therefore, they are only used on commercial vehicles (after pillar B). The application on sunroofs is accepted worldwide, regardless of the type of car.
[0016] Current European legislation requires a minimum light transmission of 75% on the windshields and 70% on the front doors. SGS THERMOCONTROL ® Venus consists of dark gray or dark green stained glass. They have all the thermal advantages of the "Vision" type glass (SGS THERMOCONTROL ® Type) with improved sun protection: - lower energy transmission values (compared to all other glass solutions), - its dark color blocks also UV radiation, which is responsible for skin irritation and discoloration of the passenger compartment, - provides greater privacy for the passengers of the vehicle (it is difficult to see through the glass from the outside). As a lamination interlayer, in particular of thickness of at most 1.3 mm, or even submillimetric, it is possible to choose in particular a sheet of thermoplastic material, for example polyvinyl butyral (PVB), ethylene vinyl acetate (EVA), polyurethane (PU ). We can mention the products called Saflex® Solutia society. The luminous glazing may comprise an electrically controllable system with variable optical properties, in particular liquid crystal, optical valve, electrochromic, thermochromic, between the guiding substrate and the protective coating or further away from the guide glass than the optical isolator. In a laminated glazing unit according to the invention, the following system may be used: said lamination / support interlayer (plastic film) / first electrode / electrically controllable optical system / second electrode / support (plastic film) / another lamination interlayer / second glass substrate or insulated substrate. As a support can be chosen a poly (ethylene terephthalate) said PET. As electrically controllable optical system may be mentioned: liquid crystals, optical valve (SPD), electrochromic, thermochromic. The liquid crystals described in the applications EP964288, EP0823653A1, EP0825478A1, EP0964288A3 and EP1405131 may be mentioned. The second glass substrate (laminated with the interlayer) may also be made of organic glass, such as a polyethylene terephthalate (PET) preferably laminated with PVB or EVA, functional PET (tinted, diffusing), or a polyester optionally with a "hard" layer such as a siloxane, - or a thermosetting PU laminated with a thermoplastic PU interlayer as described in EP132198. The second glass substrate may also be organic glass (rigid, semi-rigid) such as polymethylmethacrylate (PMMA), polycarbonate (PC).
[0017] The guiding substrate (laminated with the interlayer) can also be organic glass including flexible (rigid, semi-rigid) such as polymethyl methacrylate (PMMA), polycarbonate (PC).
[0018] The luminous glazing, preferably laminated (with mineral or organic glass), can be part of a double or triple glazing, such as a building or vehicle window (train etc) or a building or vehicle door (train etc) . In this case, it is preferable to leave a transparent zone on most of the luminous glazing, in particular a central zone with a possible (local) extraction pattern. It is also preferred to place the light glazing on the interior side of the building or the vehicle. The luminous glazing can even be part of a double glazing of a refrigerated equipment door, in particular vertical. In this case, it is preferable to leave a transparent zone on most of the luminous glazing with a possible (local) extraction pattern. The bright glazing may be the outermost of the equipment.
[0019] The face opposite to the lamination face or the bonding face may be free, or less accessible and / or used for assembly. The protective coating may comprise, better consists of a nitride, an oxide, an oxynitride preferably one of the following elements: Si, Ti, Zr, Al or one of the following elements W, Sb, Hf Ta, V, Mg, Mn, Co, Ni, Sn, Zn, Ce.
[0020] The thickness of the protective coating is adjusted to fulfill its protective function according to its nature and, indirectly, as a function of its density. Advantageously, the protective coating comprises, better consists of a layer of silica (dense) with a thickness e3 greater than 50nm, even at least 80nm or at least 100nm and better still at least 180nm and a refractive index n3 of at least 1.4 and even at least 1.42 even of at least 1.44. The (dense) silica layer may be preferably submicron and even at most 500 nm. The choice of n3 reveals that the protective coating is dense. It is devoid of through pores (of size equal to e3 or of the order of e3 is size / e3 between 1 and 2) and even it can be considered that it is essentially devoid of pores at least with a lower volume fraction at 10%, better at 5%. The dense silica layer has a solid phase (essentially) continuous, rather than a solid phase mainly in the form of (nano) particles or crystallites.
[0021] A dense silica layer (in particular not intentionally rendered porous) conventionally has a refractive index at 550nm of the order of 1.45 if deposited by physical vapor deposition and between 1.42 and 1.46 if obtained by gel sol.
[0022] In tests, the Applicant has found that with a thickness of less than 50 nm the pollutant barrier of the porous silica layer was insufficient. In the case of lamination in particular, the optical losses are gradually decreased beyond 50 nm. From 80nm we see a good improvement in guiding, 120nm guiding still improved and 230nm excellent guidance.
[0023] The porous silica layer may be a compact stack of silica nanoparticles, for example obtained by the sol-gel route, or preferably a silica layer comprising a silica matrix (otherwise known as a silica network) containing pores and preferably obtained by sol-gel route. Particularly preferred is a porous layer having a solid (substantially) continuous phase, thereby forming the dense walls of the pores, rather than a solid phase mainly in the form of (nano) particles or crystallites. To manufacture the porous gel sol layer, there are various porogenic agents. The document EP1329433 thus discloses a porous silica layer prepared from a tetraethoxysilane sol (TEOS) hydrolyzed in an acid medium with a pore-forming agent based on polyethylene glycol tert phenyl ether (called Triton) at a concentration between 5 and 50 g / I. The combustion of this pore-forming agent at 500 ° C. frees the pores. This non-localized pore-forming agent is of indeterminate form and spreads uncontrollably through the structure. Other known porogenic agents such as micelles of cationic surfactant molecules in solution and, optionally, in hydrolysed form, or of anionic, nonionic surfactants, or amphiphilic molecules, for example block copolymers. Such agents generate pores in the form of small-width channels or more or less round pores of small size between 2 and 5 nm. A porous silica layer obtained with a particulate pore-forming agent is preferred, such as polymeric beads, which in turn allows better control of the pore size, in particular access to larger sizes, better control of the pore organization in particular. a homogeneous distribution, as well as a better control of the pore rate in the layer and a better reproducibility. The polymeric beads may be a polymeric core and a mineral bark. The smallest characteristic pore size may be even more preferably greater than or equal to 30 nm and preferably less than 120 nm better than 100 nm. And preferably also, the largest characteristic pore size may be even more preferably greater than or equal to 30 nm and preferably less than 120 nm better than 100 nm. The largest dimension factor divided by smaller dimension can be less than 2 and even 1.5. In a preferred embodiment, the porous silica layer is a silica matrix with closed pores (preferably defined by the walls of the silica) in volume, and in particular an open porosity at the surface, in particular closed pores of substantially oval or substantially spherical, each of smaller dimension of at least 30 nm and greater dimension of at most 120 nm, preferably between 75 nm and 100 nm, the protective coating comprises a layer with a thickness e3 greater than the largest dimension pores and preferably submicron. The porous, closed pore volume layer is mechanically stable, it does not collapse even at high pore concentrations. The pores can be easily separated from each other, well individualized. The pores may have an elongated shape, especially in rice grain. Even more preferentially, the pores may have a substantially spherical or oval shape. It is preferred that the majority of the closed pores, or even at least 80% of them, have a given substantially identical shape, in particular elongated, substantially spherical or oval. The majority of closed pores, (even between 80% or even 95% or better all), may preferably have a smaller characteristic dimension, and preferably a larger dimension also, between 75 and 100 nm. In the porous layer, the pores may be of different sizes, although this is not preferred. The porosity may be further monodisperse in size, the pore size being then calibrated to a minimum value of 30 nm, preferably 40 nm, more preferably 50 nm and preferably less than 120 nm. The volume proportion of pores may preferably be greater than 50% and even 65% and preferably less than 85%. It should be noted, however, that the maximum volume fraction of 74 (3/0) is the theoretical maximum value applied to a stack of spheres of identical size, whatever it may be.
[0024] The guide glass or the substrate insulated with the gel sol layer and the protective coating may have been heat-treated, at a temperature greater than or equal to 450 ° C., preferably greater than or equal to 600 ° C., in particular is even a glass soaked, bending soaked. Preferably, for simplicity, the porous silica layer is a sol-gel layer and the protective coating comprises, better consists of a layer of sol-gel silica rather than a physical vapor deposition PVD including magnetron ( that is, magnetron sputtering) of the silica (or other oxide) layer are more expensive and time consuming because of the electrical insulating nature of the silica and complicating manufacture. The porous silica and / or the protective coating may be mineral or even organic mineral hybrid. The silica can be doped. The doping elements may preferably be chosen from Al, Zr, B, Sn, Zn. The dopant is introduced to replace the 15 atoms of Si in a molar percentage that can preferably reach 10%, even more preferably up to 5%. The extraction means may be on the lamination side, closer to the guiding substrate than the protective liner. In one embodiment, the porous silica layer partially covers the guide glass or the insulated substrate, thereby presenting a first so-called optical isolation zone further comprising the protective coating and the laminating interlayer, the first optical isolation preferably closer to the light source than the extraction means. And a zone, said light zone, adjacent (adjacent) and preferably contiguous (contiguous) to the first optical isolation zone comprises the extraction means (all or part) so laminated side. These extraction means, in particular formed by a diffusing layer, are directly on the guide glass, or further away than the lamination interlayer of the guide glass. Or directly on the lamination interlayer, face facing the guide glass or guide substrate or opposite face to the guide glass or the guide substrate. Optionally, the porous silica layer is discontinuous, thus presenting a second so-called optical isolation zone further comprising the protective coating and the laminating interlayer, the so-called second optical insulation zone, the extraction zone being between the first and second optical insulation zones. and the second optical isolation zone in particular contiguous with the first and the second optical isolation zone.
[0025] The diffusing layer may be a paint, in particular a lacquer, preferably: - on the second glass substrate laminated by the interlayer to the guide glass - or on the laminated laminated interlayer with the second glass substrate. The illuminated area (s) may be: - with decorative function, ambient light (in one or more distinct and / or separate patterns of shape and / or color) and / or - provide architectural lighting - provide directional lighting ( light concentrator extraction means) - with one or more signaling and / or commercial motifs (LOGO etc.) of distinct shape and / or color, joined or spaced The light extracted from the extraction pattern may flash, change of color by means of controlling the light source, for example a set of emitting diodes white or red, green, blue and preferably also white. For the extraction of light, diffusion means are used, formed either by a surface treatment of sand-blasting type glass, acid attack, enamel or diffusing paste deposit, or by a mass treatment of etching-type glass. laser. The diffusing extraction means are in the form of a surface texturing, in particular of the first or of the second face, or of a diffusing layer, in particular an enamel, a paint, an ink (white preferably or otherwise in functions areas of need) or a diffusing sticker (removable). The extraction means form a light concentrator (directed light emission) for example - reflecting means facing extraction means for reflecting the extracted rays in a given direction as described in FR2989176, lens as described in WO2005 / 018283, - first beveled glass substrate in particular with an acute angle of less than or equal to 45 °, described in FR2987043 (particularly example in Figure 2) with reflector which is a reflective surface and / or polished. The extraction means (all or part) may be on the outer face opposite to the inner face rather than under the porous silica layer occupying substantially the entire inner face.
[0026] According to one characteristic, a diffusing layer is white, in particular a paint or an enamel, having a clarity L * of at least 50, is part or forms the extraction means opposite the lamination interlayer or the side of the lamination interlayer in a zone devoid of the optical isolator. The color is defined in known manner by the parameters L *, a * and b * is measured by a spectrocolorimeter. In the case of a diffusing layer on the laminating side, the porous silica layer may be deposited only adjacent to and even contiguous with the diffusing layer (on either side) or it may also cover the diffusing layer or even a frosted area.
[0027] The diffusing layer, which is on the laminating side, is preferably with a diffuse reflection factor greater than or equal to 50% or even 80%. The diffusing layer which is opposite to the lamination, preferably has a diffuse transmission factor of greater than or equal to 50% or even 80%. The diffusing layer may be a set of diffusing patterns qualified as a grating diffusing particularly for a large desired size area as uniform as possible. This diffusing network may be formed of diffusing patterns, for example of width (average) of 0.2 mm to 2 mm, preferably less than 1 mm and of micron thickness for example from 5 to 101 m. The (average) spacing between the patterns can be 0.2 to 5mm. To form this network we can texture a layer. In the light zone or zones (on the opposite side to the face with extraction means such as enamel and / or on the side of the face with extraction means such as enamel), the lighting may be of the type lambertian and non-directional, along an axis of propagation of light. Thus, the luminance has the advantage of being substantially equal whatever the angle of observation. Preferably, the guide glass or the guiding substrate coated with the extraction means, in particular enamel, has a light transmission of less than 45% or even 40% or even 35%. The extraction means, in particular enamel, extend, for example over the entire face of the glass or guide substrate, discontinuously or according to geometric shapes sparse curved lines and / or straight. The enamel is for example fractal geometry. According to another characteristic, the extraction means extend discontinuously and delimits dark areas including patterns of geometric shapes sparse curved lines and / or straight lines, in particular of length (greater dimension) at least centimeter.
[0028] The light zone can cover a part of the surface, thus leaving at least a first dark area, that is to say non-luminous area can cover a part of the surface, thus leaving at least a first zone, dark area that is chosen among a transparent area (clear glass ...) or a decorative area with an opaque and / or colored coating such as the first coating, or a reflecting area including mirror for example formed by a silver coating covered with a protective paint. The mirror is, for example, the SGG Miralite product from SAINT-GOBAIN GLASS, with an oxidation protection paint, the silvering of the mirror being disposed: on the same face as the extraction means (enamel, paint ) or on an opposite side - on the lamination side. As a variant, the mirror is based on chromium, such as the SGG Mirastar product from SAINT-GOBAIN GLASS, the chromium being on the same face as the extraction means (enamel, paint) or on an opposite face. on the side of the lamination or on the outer or outer face. The maximum width, the width corresponding to the smallest surface dimension of this light zone (of any possible shape), may preferably be less than 200 mm or even less than or equal to 100 mm, in particular to leave a large dark area surface. . The width is constant or variable. The light zone may be a peripheral zone, in particular along at least one edge, for example at least one strip or a drawing, while the dark zone is more central (and further away from the light source). The diffusing layer, in particular enamel, may be a continuous layer on the surface, with a width of less than 200 mm, even 100 mm and even more preferentially less than or equal to 50 mm, or be discontinuous and formed of a set of fine patterns, width (minimum dimension of the pattern) less than 200 mm, or even 100 mm and more preferably less than or equal to 50 mm. The extraction patterns, diffusing are for example geometric: rectilinear or curved strip, concentric circles, L. etc. The patterns are identical or distinct, parallel to each other or not, with a distance between them identical or not. In a preferred embodiment, the diffusing layer (all or part of the extraction means) consists of particles agglomerated in a binder, said particles having a mean diameter of between 0.3 and 2 microns, said binder being in a proportion between 10 and 40% by volume and the particles forming aggregates whose size is between 0.5 and 5 microns. This preferred diffusing layer is particularly described in the application W00190787.
[0029] The particles may be chosen from semi-transparent particles and preferably inorganic particles such as oxides, nitrides, carbides. The particles will preferably be chosen from oxides of silica, alumina, zirconia, titanium, cerium, or a mixture of at least two of these oxides. For the extraction of light, diffusion means are used. formed either by a superficial treatment of sandblasting type glass sheet, acid etching, enamel or diffusing paste deposit, or by a mass treatment of laser etching type glass. The diffusing layer (all or part of the extraction means) may be composed of elements containing particles and a binder, the binder making it possible to agglomerate the particles together. The particles may be metallic or metal oxides, the particle size may be between 50 nm and 11 μm, preferably the binder may be inorganic for heat resistance. The diffusing layer (all or part of the extraction means) may be composed of elements containing particles and a binder, the binder making it possible to agglomerate the particles together. The particles may be metallic or metal oxides, the particle size may be between 50 nm and 11 μm, preferably the binder may be inorganic for heat resistance. In a preferred embodiment, the diffusing layer (all or part of the extraction means) consists of particles agglomerated in a binder, said particles having a mean diameter of between 0.3 and 2 microns, said binder being in a proportion between 10 and 40% by volume and the particles forming aggregates whose size is between 0.5 and 5 microns. This preferred diffusing layer is particularly described in the application W00190787. The particles may be chosen from semi-transparent particles and preferably inorganic particles such as oxides, nitrides, carbides.
[0030] The particles will preferably be chosen from oxides of silica, alumina, zirconia, titanium, cerium, or a mixture of at least two of these oxides. For example, a diffusing mineral layer (all or part of the extraction means) of about 10 μm is chosen. Advantageously, a luminous zone is a solid enamel (thus a solid zone as opposed to a network of dot-like points like millimeter points) in particular of length (greater dimension) at least centimeter.
[0031] According to one characteristic, the enamel extraction has the following composition - between 20 and 60 (3/0 by weight of 5i02, - 10 to 45 (3/0 by weight of refractory pigments, including h02, including micron size preferably not more than 20% by weight of alumina and / or zinc oxide The TiO 2 pigments make the enamel sufficiently opaque (to visualize the enamel in the off state) and lower the IL Examples of enamel extraction composition may be enamel under the name Ferro 194011 sold by the company FERRO, the reference AF5000 marketed by the company JM, the reference VV30-244-1 marketed by Pemco are very whites with a gloss greater than 20 and have a low light transmittance of less than 40 ° V. It may be desirable for the light to be visible only on the outer or outer side thereof, for which purpose a reflector or an opaque element on the means of extract at the laminating side, (diffusing layer in particular), - using a reflector or an opaque element on the laminating side facing the extraction means on the outer or outer face - sufficiently increasing the thickness of the diffusing layer (laminating side). A diffusing enamel / masking enamel system can be used according to the one-way vision method with discrete enamel patterns described in WO2012 / 172269 or EP1549498. As a light source it is possible to choose an extractor optical fiber, with a side emitter face (coupled to a primary light source which is typically a diode). For example, 3M optical fiber, 3MTm Precision Lighting Elements, is used. Diodes are preferred. The diodes may be (pre) encapsulated, that is to say comprising a semiconductor chip and an envelope, for example epoxy resin or PMMA, encapsulating the chip and whose functions are multiple: diffusing element or focus, wavelength conversion. The envelope is common or individual. Advantageously, the diodes are arranged to inject light through the edge of the glass or guide substrate along two parallel opposite sides. The diodes may preferably be single semiconductor chips, for example of size of the order of one hundred of 1 or 1 mm. Their width is preferably less than the thickness of the first glass substrate, especially if not laminated on the second side.
[0032] The diodes may optionally comprise a protective envelope (temporary or not) to protect the chip during handling or to improve the compatibility between the materials of the chip and other materials.
[0033] The diode may be chosen in particular from at least one of the following light emitting diodes: a side-emitting diode, that is to say parallel to the (faces of) electrical contacts, with a lateral emitter face relative to the support, a diode whose main direction of emission is perpendicular or oblique with respect to the emitting face of the chip. The emission diagram of a source can be lambertian. Preferably, the distance between the chips and the first sheet is less than or equal to 2 mm. For optical insulation taking into account the skin thickness, it is preferred that when n2 is less than or equal to 1.3, e2 is at least 600nm - when n2 is less than or equal to 1.25, e2 is at least 500nm - when n2 is less than or equal to 1.2, e2 is at least 400nm. For safety e2 is chosen at least 600nm and even at least 700nm or at least 800nm.
[0034] The substrate or guiding glass used may be any type of flat glass, (possibly curved by bending processes known to those skilled in the art, when it comes to coating curved surfaces). It may be monolithic glasses, that is to say composed of a single sheet of mineral glass, which may be produced by the "float" method making it possible to obtain a perfectly flat and smooth sheet, or by means of drawing or rolling processes. Examples of glass materials include float glass (or float glass) of conventional soda-lime composition, optionally hardened or tempered thermally or chemically, an aluminum or sodium borosilicate or any other composition.
[0035] The glass of the substrate or guide glass may be clear, extra-clear, very low in iron oxide (s). These are, for example, glasses marketed in the "DIAMOND" range by SAINT-GOBAIN GLASS. The substrate of the substrate or guide glass may be a glazing of silicosodocalcic glass, in particular extraclear, may have: a transmission of the light radiation greater than or equal to 91% or even greater than or equal to 92% or even 93% or 94% at 550 nm or preferably over the entire visible range, and / or a reflection of the light radiation less than or equal to 7%, or even less than or equal to 4%, at 550 nm or preferably over the entire visible range.
[0036] The coupling slice can be shaped, automotive shaping (rounded), straight. The first glass substrate can be tempered and / or curved even after being coated.The first glass substrate with the sol gel layer and the protective coating may have been heat-treated, at a temperature greater than or equal to 450 ° C, preferably higher or equal to 600 ° C, in particular is even a tempered glass, tempered bending. The first glass substrate can be tempered and / or curved even after being coated. The first glass substrate with the gel sol layer and the protective coating may have been heat-treated, at a temperature greater than or equal to 450 ° C, preferably greater than or equal to 600 ° C, in particular is even a tempered glass, hardened bending. The thickness of the first glass substrate is preferably between 2 and 19 mm, preferably between 4 and 10 mm, more particularly between set 9 mm.
[0037] The laminated glazing unit may have the following configuration: the slice of the guide glass has a marginal recess passing through the thickness where the source is housed, or the second substrate is protruding from the injection slice of the first sheet, creating a lateral recess As an example, the luminous glazing is intended for: - a building glazing, such as an illuminating facade, an illuminating window, a ceiling lamp, a slab of floor or illuminating wall, an illuminated glazed door, an illuminating partition , illuminating ceiling, stair step, railing, railing, counter, - a transport vehicle, such as an illuminated side window or an illuminated glass roof or a light window or a rear window, a glass door illuminating, in particular for the transport of private individuals, such as automobile, truck, or in common, such as trains, subways, trams, buses or water or air vehicles (aircraft), - street or urban lighting, - glazing of street furniture, such as illuminated glasswork for bus shelters, balustrades, display stands, showcases, shelves, glasshouses, - glazing interior furniture, such as an illuminating bathroom wall, an illuminating mirror, an illuminated glass part of a piece of furniture, - a glazed part, in particular a door, a glass shelf, a lid for refrigerated domestic or professional equipment. The invention also relates to a particularly laminated partition, door (framed or not, including laminated), window including double or triple glazing, tablet or door (including double glazing) refrigerated domestic equipment or professional glazing furniture , in particular closet door, ceiling, railing, wall panel, wall tile, stair step, mirror, counter, showcase incorporating a luminous glazing according to the invention. The partition can be fixed or in the form of sliding panels, for example mounted on rails. The door can be an indoor or outdoor door or a shower door.
[0038] For a partition wall, shelf, shop window or company premises, the geometric shape of the combination of enamel and transparent glass surface will advantageously correspond to the logo of the company. In a vehicle, the radiation extraction / conversion (as well as the type and / or the position and / or the number of the diodes) is adjusted for: - ambient lighting, reading, especially visible inside of the vehicle, - a luminous signal, in particular visible on the outside: - by activation of remote control: detection of the vehicle in a parking lot or other, indicator of (un) locking of doors, or - safety signaling, for example as stop lights on the rear, - a substantially uniform illumination over the entire extraction surface (one or more extraction zones, common or separate function). The light can be: - continuous and / or intermittently, - monochromatic and / or plurichromatic. Visible inside the vehicle, it can have a function of night lighting or display information of any kind, such as drawing, logo, alphanumeric signage or other signs. As decorative patterns, one can form for example one or more light strips, a peripheral light frame.
[0039] It is possible to make a single extraction face (internal to the vehicle preferably). The insertion of diodes into these glazings makes it possible to provide the following additional signaling functions: - display of indicator lights for the driver of the vehicle or the passengers (example: engine temperature warning indicator in the automobile windshield, warning lamp for operating the electric defrosting system, windows, etc.), - display of warning lights for persons outside the vehicle (example: warning lamp for activating the vehicle alarm in side windows), - illuminated display on the windows of vehicles (eg flashing light on emergency vehicles, safety display with low power consumption indicating the presence of a vehicle in danger). The glazing may include a receiving diode of control signals, especially in the infrared, for remote control of the diodes. The glazing is intended to equip any vehicle: - Side window of a land vehicle, including automobile, utility vehicle, truck, train, including the functional element which is a maintenance part of a window lifter system or with the cover hubcap, - mobile or fixed roof of a land vehicle, including automobile, commercial vehicle, truck, train, with a first sheet possibly curved, including a laminated glazing, - windshield of a land vehicle, including automobile, vehicle utility, truck, train, in particular with the one or more light areas (forming a "HUD" sign, for example) in the enamel border or in the vicinity, rear window in particular in the enamel border or in the vicinity, - porthole, windshield of an aerial vehicle, - window panes, roof, aquatic vehicle, boat, submarine - double or triple glazing in a train, bus. The glazing comprises a masking element of the source and any stray light (in particular opposite the extraction face, close to the coupling zone), and / or masking of the fixing of the glazing to the bodywork of the vehicle by the second face, the masking element possibly being the polymeric encapsulation (sufficiently opaque black), - a sufficiently opaque enamel, on the periphery of the second face and / or on the first face - and / or a surface reflective (layer ...) on the periphery of the bonding face and / or on the inner face. As already seen, the luminous glazing, in particular of a vehicle, may comprise a polymeric encapsulation, in particular of thickness 0.5 mm, better 2 mm, to several cm, obtained by overmolding and preferably between the encapsulation and the glazing, in particular made of mineral glass. a primer layer, mono, bi or tri-component, for example based on polyurethane, polyester, polyvinyl acetate, isocyanate. In vehicle applications, the encapsulating material is usually gray or black (for aesthetic and / or masking purposes). The encapsulation may be polyurethane, especially PU-RIM (Reaction In Mold in English). Other overmoulding materials are: flexible thermoplastics: thermoplastic elastomer (TPE), in particular compounds based on styrene ethylene butadiene styrene SEBS / polypropylene (PP), thermoplastic TPU, polypropylene PP / EPDM, polyvinyl chlorine (PVC), ethylene-propylene-diene terpolymer (EPDM), - rigid thermoplastics: polycarbonate (PC), polymethyl methacrylate (PMMA), polyethylene (PE), polypropylene (PP), polyamide (PA66), acrylonitrile butadiene styrene (ABS), and their alloys ABS-PC, polystyrene (PS), acrylonitrile styrene acrylate ASA. The overmoulding material can be colored, loaded with glass fibers. The primer layer, mono, bi or tri-component, is for example based on polyurethane, polyester, polyvinyl acetate, isocyanate ..., for example thick from 5 to 50 μm or more, between the encapsulation and the glazing. especially in mineral glass, because this layer promotes adhesion to a mineral glass. The overmolding also provides a good aesthetic finish and allows to integrate other elements or functions: - overmolding frames, reinforcing inserts or inserts for fixing the glazing, in particular for the opening windows, - multiple lip seal profile ( double, triple ...), crashing after mounting on the body, - hubcap. A tubing, in other words a closed cell sealing profile, can also be attached to the overmoulded element.
[0040] Preferably for a roof, a flush encapsulation is made, that is to say flush with one of the faces of the luminous glazing. The encapsulation may be single-sided (on one face of the glass or guiding substrate) or biface equally on the edge and even triface (on opposite face to face gluing or laminating) Alternatively, the vehicle glazing comprises a pre-assembled polymeric seal, preferably elastomer, especially TPE (for thermoplastic elastomer), or EPDM. The seal can be adhesive for its maintenance. The seal may preferably simply hold by pinching or by snap or clipping (two half-frames for example). The seal can be single-sided, two-sided, triface. The seal can form a frame. The seal can be of any shape: L, U ... The seal can be removable at any time. It may comprise by one or more lips constrained after fixation. Naturally, the invention also relates to a vehicle incorporating the glazing previously defined.
[0041] On the other hand, the invention also relates to a method of manufacturing the light glazing as described above comprising the following successive steps: (1) on the face of a glass substrate (guide glass or guiding substrate) the application in a first layer of a first precursor sol of the material constituting the silica layer of the doped or non-doped optical isolator, in particular a hydrolysable compound such as a halide or a silicon alkoxide, in a first solvent, in particular a aqueous solvent and / or alcoholic, mixed with a solid polymeric pore-forming agent in the form of particles, in particular in aqueous suspension, the particles preferably being of size (smaller and / or greater characteristic dimension) greater than or equal to 50 nm, in particular between 75 and 100. nm, and preferably less than 200nm better 130nm, (2) a drying of the layer, said dried layer, preferably at room temperature or at most 110 ° C , preferably of duration of not more than 1h, in particular eliminating the solvent, (3) on the dried layer, applying a second layer of a second precursor sol of the material constituting the silica layer forming the protective coating doped or non-doped, in particular a hydrolyzable compound such as a halide or a silicon alkoxide, in a second solvent, especially aqueous and / or alcoholic solvent, (4) a heat treatment at least 450 ° C., in particular simultaneous densification of the first and second layers and removal of the blowing agent, preferably first heat treatment (or first heat treatment of more than 200 ° C) (5) cooling preferably to room temperature eventually slowly to avoid as much as possible risk of cracks (6) the application of the first laminating interlayer of thermoplastic material to the protective coating (7) (7) the application of a glass or organic substrate, or Intral (other glass substrate, second glass substrate) (8) a laminating thermal cycle. The deposition (1) and / or (3) on the substrate can be carried out by spraying, by immersion and drawing from the silica sol (or "dip coating"), by centrifugation (or "spin coating"), by casting ("Flow-coating"), by roll ("roll coating"). It is thus possible to choose silica prepared from tetraethoxysilane (TEOS), sodium silicate, lithium or potassium or hybrid materials obtained from organosilane precursors whose general formula is R2n Si (OR1) 4- n with n an integer between 0 and 2, R1 an alkyl function of the type CxH2x, 1, R2 an organic group comprising, for example, an alkyl, epoxy, acrylate, methacrylate, amine, phenyl or vinyl function. These hybrid compounds can be used mixed or alone, in solution in water or in a water / alcohol mixture at an appropriate pH. As a hybrid layer, it is possible to choose a layer based on methyltriethoxysilane (MTEOS), an organosilane with a non-reactive organic group. MTEOS is an organosilane which has three hydrolyzable groups and the organic part of which is a methyl, nonreactive. Preferably, the second sol is MTEOS / TEOS alcohol base, preferably in an isopropanol, especially when the target thickness e3 is less than 300nm for optimal wetting, better than with an aqueous solvent and even the first soil is TEOS in an aqueous solvent and the polymer particles in aqueous suspension and.
[0042] When the second sol is MTEOS / TEOS in an ethanol solvent it is preferred to limit the thickness e3 to about 120 nm even at 100 nm. However, there is more choice of second sol if e3 is at least 300 nm and better still at least 400 nm, for example MTEOS / TEOS in aqueous base, especially in acid solution (HCl), for example at pH2. The heat treatment (first and second layer or even with enamel or even paint) may be at least 500 ° C, or even at least 600 ° C for a period less than or equal to 15 minutes, preferably 5 minutes and is followed by quenching and / or bending / forming. Indeed, the two silica layers have the capacity to withstand heat treatments at high temperature without cracking and without noticeable deterioration of its optical properties of its durability Heat treatment, including bending / forming, can be followed by an operation quenching, at least 600 ° C for a period of less than or equal to 5 minutes. The heat treatment can be bending / forming between 650 and 670 ° C followed by a quenching operation. The heat treatment can be bending / forming between 600 and 650 ° C between 2 and 4 minutes (without quenching). It is preferred that the heat treatment and / or the cooling is not too abrupt to avoid the risk of cracks in the layers. It is preferred that the material of the blowing agent is removed before all is consolidated and densified. The refractive index of the porous silica layer can be tailored to the pore volume. The following relation can be used for the calculation of the index: n = f.ni + (1-f) .npores where f is the volume fraction of the constituent material of the layer and n1 its refractive index and n pores is the pore index generally equal to 1 if they are empty. In particular, a foaming agent may be selected from one of the following polymers: polymethyl methacrylate (PMMA), methyl (meth) acrylate / (meth) acrylic acid copolymers, polycarbonate polymers, polyester, polystyrene, etc. , or a combination of several of these materials. The solid pore-forming agent may advantageously comprise beads which are preferably polymeric, in particular of the PMMA type, methyl methacrylate / acrylic acid copolymer, polystyrene. The solid pore-forming agent may be a latex which is preferably acrylic or styrene, stabilized in water. by a surfactant, especially anionic surfactant. It is quite possible to make a micrometric protective coating, and preferably at most 311m. The details and advantageous features of the invention will now be apparent from the following nonlimiting examples, with the aid of the figures: FIGS. 1 to 10 are schematic and partial cross-sectional views of light glazings with optical isolator protected in several modes of embodiment of the invention. The elements are not to scale.
[0043] EXAMPLES OF LUMINOUS GLAZING FIG. 1 shows a partial sectional view of a luminous glazing 100 with protected optical isolator in a first embodiment comprising: a first glass substrate 1, called guide glass, which is here a form glazing flat rectangular or curved variant, of clear or extraclear silicosodocalcic glass, (of about 6 mm for example for the building or of at most 3 mm for the automobile), of refractive index n1 of about 1.5 to 550 nm , TL at least 90%, with first 11 and second main faces 12 and a first slice 13, - a light source 4, here a set of light-emitting diodes on a printed circuit board PCB 41, optically coupled at the said guide wafer 13, the guide glass 1 guiding the light emitted by the diodes preferably spaced by at most 2 mm from the guide wafer, preferably centered on the wafer 13 and of a width less than the thickness of the wafer,glass 1, - light extraction means 6 associated with the guide glass here on the second main face 12, said outer face, which are a preferably white diffusing layer having a clarity L * of at least 50, preferably a diffusing enamel, or alternatively a frosted surface of the second face or an optical concentrator, extraction means in several diffusing patterns forming a plurality of light areas (or a uniform light zone if sufficiently close) or alternatively a light area full for example unique and central. The first main face 11, referred to as the internal face, comprises successively: a porous silica gel sol layer 2 with a thickness e2 of 800 nm and a refractive index n2 at 550 nm of at most 1.35 at 550 nm. porous silica layer 2 being a silica matrix with closed and even surface-open pores, in particular of substantially oval or substantially spherical shape, each smaller in size of at least 30 nm and larger in size by at most 120nm, preferably between 75nm and 100nm, substantially covering the first face 11, inner surface 21 and outer surface 22 - a protective coating, mineral and transparent, 3 directly on the porous silica layer and covering the entire porous silica layer here, which is a layer of silica sol gel with a thickness e3 greater than 50 nm, better at 180 nm, and a refractive index n3 of at least 1.4 to 550 nm, inner surface 31 and outer surface 32, - a spacer of leaflet ge 7 thermoplastic material preferably PVB, EVA, or PU, generally submillimetric transparent for example clear inner surface 71 and outer surface 72, - a second glass substrate 1 ', mineral glass, for example identical to the guide glass with a main bonding face 11 'laminate interlayer side and an opposite face 12' The bonding face 11 'carries directly (or via an adhesion primer) a first decorative coating and / or masking 5, for example a continuous layer of paint and preferably a lacquer, colored (white, black included) preferably of color distinct from the extraction means, or arranged in disjoint or continuous discrete colored patterns in a color or in distinct colors, for example manufactured by masking or by serigraphy.
[0044] The guide glass may be quenched by the heat treatment to form the porous sol gel silica layer and the dense sol gel silica layer. The glazing can be bomb tempered by heat treatment to form the porous silica sol gel layer and the silica gel sol gel layer. For example, the heat treatment is a bending / forming between 650 and 670 ° C followed by a quenching operation. The heat treatment is a bending / forming between 600 and 650 ° C between 2 and 4min.The heat treatment, including bending / forming, can be followed by a quenching operation, at least 600 ° C for a period less than or equal to at 5 minutes. Extraction enamel 6 has, for example, the following composition: between 20 and 60% by weight of SiO 2, 10 to 45% by weight of refractory pigments, including hO 2, in particular of micron size preferably not more than 20% by weight of alumina and / or zinc oxide, the TiO 2 pigments make the enamel sufficiently opaque to visualize the enamel in the off state and lower the examples of enamel composition may be enamel under the name Ferro 194011 marketed by the company FERRO, reference AF5000 marketed by the company JM, the reference VV30-244-1 marketed by Pemco.The enamel is here screen printed or As a printed variant, it is conceivable that the heat treatment used to manufacture the sol gel layers is used to bake the enamel The extraction means may form a plurality of light patterns, for example in broad peripheral bands and / or more discrete patterns, in particular geometric patterns. They are a decoration, a sign, a LOGO, a mark. The illumination may be continuous or flashing and / or of variable color.
[0045] Other diodes can be added to the opposite wafer (not shown here) especially in the case of a large glazing unit and / or with several spaced centimeter units. In order to see the continuous background of lacquer 5 (or enamel or other paint) it may be desired that the light zone is not distributed substantially over the entire glazing (avoid extraction over the entire bearing face of the extraction means). Alternatively, the diffusing layer may be directly on the inner face 11: - under the porous silica layer optionally with a rupture or heterogeneity of thickness on each edge 63, 64 and / or the outer surface 62. - if the porous layer 2 becomes discontinuous (facing, directly) under the paint 5 possibly to absorb light extracted in the opposite direction to the outer face. The face 12 'opposite to the bonding face 11 "may be a free surface of the luminous glazing, visible or even accessible (to the touch) .35 After installation of the luminous glazing this free surface may be opposite a glass wall of a building (wall, partition, ceiling, roof) or even a vehicle After installing the luminous glazing, this free surface may be opposite an opaque wall of a building (wall, partition, ceiling, roof) or The luminous glazing 100 forms, for example, to form a partition, a ceiling, a floor or a decorative wall panel The second substrate 1 'coated with lacquer 5 may be the Planilac or Decolac product of the Applicant, with a wide range of available shades (hot, cold metallized) One can even insert an electrically controllable system with variable optical properties ie the following sequence on the protective coating: first PVB or EVA / first transparent electroplating ode such as PET / first transparent electrode including ITO or multilayer silver / liquid crystal layer / second transparent electrode including ITO or silver multilayer / second transparent electrode support such as PET / second PVB or EVA. In the off state, the system is opaque and in the state the system is transparent and reveals the first coating 5.
[0046] FIG. 2 shows a partial sectional view of a luminous glazing 200 with protected optical isolator in a second embodiment comprising: a glass substrate 1, called a guiding substrate, which is a glazing here in planar rectangular shape or in a variant curved, clear or extraclear silicosodocalcic glass, (about 6mm for example for the building or at most 3mm for the automobile), of refractive index n1 of about 1.5 to 550 nm, TL of at least 90%, with a first main face 11 called the connecting face, and a second opposite main face 12 called outer face, and a first wafer 13, - a light source 4, here a set of light-emitting diodes on a map of printed circuit board called PCB 41, optically coupled to the said guide portion 13 of the guide substrate, the guiding substrate guiding the light emitted by the diodes preferably spaced at most 2mm from the guide wafer, preferably centered on the wafer and of width less than the thickness of the glass 1; - Light extraction means 6 associated with the guide substrate here on the connecting face 12, which are a preferably white diffusing layer having a clarity L * of at least 50, preferably a diffusing enamel, or variant an optical concentrator, extraction means in a solid light zone for example single and central or alternatively in several scattering patterns forming a plurality of light areas (or a uniform light zone if sufficiently close). a lamination interlayer 7 made of thermoplastic material, preferably PVB, EVA, or PU, generally submillimetric, transparent for example clear, extraclear of inner surface 71 and outer surface 72, alternatively carrying extraction means (locally), or integrating extraction means (scattering particles, etc.) - another glass substrate 1 'made of mineral glass, for example identical to the guiding glass with a lamination main face 11' laminating interlayer side and an opposite face 12 'Alternatively, the guiding substrate 1 is made of organic glass, for example PC (preferably with laminating interlayer 7 PU), PMMA (preferably with laminating interlayer 7 PVB). The laminating face 11 'comprises successively: a porous silica gel sol layer 2 with a thickness e2 of 800 nm, of refractive index n2 at 550 nm of at most 1.35 at 550 nm, the porous silica layer 2 being a silica matrix with closed pores 20 and open at the surface, in particular of substantially oval or substantially spherical shape, each of smaller dimension of at least 30 nm and larger dimension of at most 120 nm, preferably between 75 nm and 100 nm substantially covering the face 11 ', inner surface 21 and outer surface 22 - a protective coating, mineral and transparent 3 directly on the porous silica layer and covering the entire porous silica layer, here which is a layer of silica sol gel with a thickness e3 greater than 50 nm, better at 180 nm, and a refractive index n3 of at least 1.4 to 550 nm, inner surface 31 and outer surface 32, the other glass substrate 1 'is described as an isolated substrate (optically). The face opposite to the lamination face 11 'carries directly (or via an adhesion primer) a first decorative coating and / or masking 5', for example an enamel (rather if mineral glass 1 ') or a paint, for example manufactured by masking or screen printing, in a pattern on the periphery or even elsewhere (central zone etc) .35 It can be used for part of its length, especially for masking (absorbing) stray light coming directly from the diodes at large angles . Alternatively, as in the glazing 100, the face opposite to the lamination face 11 'carries directly (or via an adhesion primer) a first decorative coating and / or masking 5, for example a continuous layer of paint and preferably a lacquer, colored (white, black included) preferably of a color distinct from the extraction means, or arranged in disjoint or continuous discrete colored patterns in a color or in distinct colors, for example manufactured by masking or by screen printing. The insulated substrate 1 'coated with lacquer 5' may be the product Planilaque or Decolac (water based paint) of the Applicant, with a wide range of available colors (hot, cold metallized). The insulated substrate can be tempered, filmed for its protection (on the lacquer). The face 12 'with the lacquer can be printed and coated with lacquer and / or textured for an adjacent frost, contiguous to the lacquer. The insulated substrate 1 'can be quenched by the heat treatment to form the porous sol gel silica layer and the dense sol gel silica layer. The glazing can be bomb tempered by heat treatment to form the porous silica sol gel layer and the silica gel sol gel layer.
[0047] For example, the heat treatment is a bending / forming between 650 and 670 ° C followed by a quenching operation. The heat treatment is a bending / forming between 600 and 650 ° C between 2 and 4min.The heat treatment, including bending / forming, can be followed by a quenching operation, at least 600 ° C for a period less than or equal to at 5 minutes.
[0048] Extraction enamel 6 has, for example, the following composition: between 20 and 60% by weight of SiO 2, 10 to 45% by weight of refractory pigments, including hO 2, in particular of micron size preferably not more than 20% by weight of alumina and / or zinc oxide.
[0049] The TiO2 pigments make the enamel sufficiently opaque to visualize the enamel in the off state and lower the IL Examples of enamel composition may be enamel under the name Ferro 194011 marketed by the company FERRO, the reference AF5000 marketed by the company JM, the reference VV30-244-1 marketed by Pemco.35 The enamel is here screen printed or alternatively printed. It can be envisaged that the heat treatment used to manufacture the gel sol layers is used to cook the enamel. The extraction means can form a plurality of light patterns, for example wide peripheral bands and / or more discrete patterns, in particular geometric ones. The luminous motifs form a decoration, a sign, a LOGO, a mark. The illumination may be continuous or flashing and / or of variable color. Other diodes can be added to the opposite wafer (not shown here) especially in the case of a large glazing unit and / or with several spaced centimeter units. In order to see the continuous background lacquer (or enamel or other paint) it may be desired that the light area is not distributed substantially over the entire glazing (avoid extraction on the entire bearing face of the extraction means). Alternatively, the diffusing layer may be directly on the bonding face 11 - under the porous silica layer, possibly with a break or heterogeneity of thickness on each edge 63, 64 and / or the outer surface 62 if the porous layer 2 becomes discontinuous (opposite, directly) under the paint possibly making it possible to absorb light extracted in the opposite direction to the first face. The face 12 'opposite the bonding may be a free surface of the monolithic light glazing is visible or even accessible (to the touch). After installation of the luminous glazing, this free surface may be facing a glazed wall of a building (wall, partition, ceiling, roof) or even of a vehicle. After installation of the monolithic luminous glazing, this free surface may be opposite an opaque wall of a building (wall, partition, ceiling, roof) or even of a vehicle. The light glazing 100 forms for example to form a partition, a ceiling, a floor, a wall decorative panel. It is even possible to insert an electrically controllable system with variable optical properties, ie the following sequence on the protective coating: first PVB or EVA / first transparent electrode support such as PET / first transparent electrode, especially ITO, or multilayer silver / crystal layer liquid / second transparent electrode including ITO or multilayer silver / second transparent electrode support such as PET / second PVB or EVA. In the off state, the system is opaque and in the state the system is transparent and reveals the first coating 5. FIG. 3 shows a partial sectional view of a light glazing 300 with an optical isolator protected in a third embodiment. Only differences from the first mode are described. The bright glazing 300 differs as follows. The porous silica gel sol layer 2 and the protective coating 3 are discontinuous (forming a first and second optical isolation zone 24, 25 separated by a discontinuity 23), leaving an area of the inner face directly in contact with the interlayer lamination 7 preferably clear, extraclair. The discontinuity may be surrounded by the optical isolator 2 (closed pattern). The extraction means 6 are formed by the white chosen paint or lacquer on the bonding face 11 '(or alternatively a white enamel). Alternatively on the bonding side the lacquer is white in the area opposite the discontinuity and elsewhere there is one or more areas of bright color for example. Alternatively, the side face 71 of the bonding side or inner face side 72 of the lamination interlayer 7 comprises a diffusing layer, for example is a preferably printed PVB locally. The protective coating 2 in a sol-gel silica layer having a index of about 1.45 can remain a full layer substantially covering the internal face 11 in the discontinuity 23. FIG. 4 shows a partial sectional view of a luminous glazing 400 with protected optical isolator in a fourth embodiment.
[0050] Only the differences from the second mode are described. The luminous glazing 400 differs as follows. The insulated substrate 1 'has on its face 12' opposite to the lamination face 11 'a tinted element 51 for example a tinted PET glued by an optical adhesive or by a lamination interlayer (PVB etc.), especially clear, extraclair.
[0051] The extraction means 6 can be moved on the outer face side 12. FIG. 5 shows a partial sectional view of a luminous glazing unit 500 with protected optical isolator in a fifth embodiment. Only differences from the first mode are described. The luminous glazing 500 differs as follows.
[0052] In replacement (or alternatively in addition) of the decorative paint 5 is inserted an electrically controllable system with variable optical properties 52 is the following sequence between the protective coating 3 and the bonding face 11 ': the first spacer 7 (PVB or EVA) / a first transparent electrode support 81 such as PET / first transparent electrode 82 in particular ITO or silver multilayer / liquid crystal layer 83 / second transparent electrode 83 in particular ITO or silver multilayer / second transparent electrode support 85 such as PET / second PVB or EVA 7 '. In the off state, the system is opaque and in the state or system is transparent. The second glass 1 'is for example tinted. Figure 6 shows a partial sectional view of a light glazing 600 with protected optical isolator in a sixth embodiment. Only the differences from the second mode are described. The luminous glazing 600 differs as follows. The first decorative coating and / or masking is replaced by a mirror layer 50 based on silver with a protective overlay or a chromium-based spy mirror. We thus form an illuminating mirror. Preferably the mirror zone is at least central (if partial mirror on the face 12 ') and the light zone (s) 6 are more peripheral (solid bands, discontinuous from discrete patterns ..). Diodes can be added to the opposite wafer (not shown) FIG. 7 shows a partial sectional view of a light glazing 700 with protected optical isolator in a seventh embodiment. Only the differences from the third mode are described. The luminous glazing 700 differs as follows. The second glass substrate 1 'is made of organic glass, for example a tinted PET 1'. The side face on the inside of the laminating interlayer 7 comprises a diffusing layer 6 directly on the inner face 12 (or alternatively on the protective coating 3 or in contact with 1 '), for example is a preferably printed PVB locally. . For example, a closet furniture door is thus formed. Fig. 8 shows a partial cross-sectional view of a light glazing unit 800 with a protected optical isolator in an eighth embodiment. Only the differences from the third mode are described. The bright glazing 800 differs as follows. For example, by selective deposition, by screen printing (enamel, etc.), the extraction means 6, in particular the diffusing layer, are formed directly on the inner face 12 or on the protective coating 3 as a variant. The laminating interlayer 7 covers the laminated extraction enamel 6 a second organic glass substrate 51 'tinted (PET) or diffusing. FIG. 9 shows a partial view in section of a luminous glazing 900 with protected optical isolator in a ninth embodiment. Only the differences from the second mode are described. The luminous glazing 900 differs as follows. The guide substrate 1 has a local longitudinal recess of the coupling wafer 13 for accommodating the diodes 4 which have a lateral emitting face. Glue 9 'on the rear face of the PCB 41 serves to fix the PCB assembly 41 + diodes 4 on the lamination face 11'.
[0053] The face 12 'opposite to the bonding face 11' is for example fully frosted 120 or partially, like the Satinovo glass of the Applicant. This luminous glazing 900 is used for example in the building as a partition. Figure 10 shows a partial sectional view of a light glazing 1000 with optical isolator protected in a tenth embodiment. Only the differences from the ninth mode are described. The luminous glazing 1000 differs as follows. The optical isolator 2 and the protective coating 3 are on the guide glass 1.
[0054] The guide glass 1 is about 2 mm, especially for a vehicle application. The luminous glazing exhibits an opaque encapsulation primer 91 and a polymeric encapsulation made of PU 9, of biface type (flush side opposite to the bonding face 11 '). The space between the emitting face 4 and the coupling wafer 13 (rounded, for automotive-type shaping) is filled by optical adhesive 9 'fixing the diodes. An opaque coating 5 'as an enamel is peripheral of the bonding face 12' to promote the masking of the escaping stray light. 3 015 92 6 38 EXAMPLES OF PROTECTED OPTICAL ISOLATORS On a first main face of four float glass silicosodocalcic 5 thickness 6mm, numbered El to E4, such as the Diamant glass of the company Saint Gobain Glass France, four optical insulators are formed each, in the form of a porous silica gel sol layer having a thickness e2 of about 800 nm, with about 18% solids content and about 80% porosity; refraction n2 of about 1.15 to 550 nm, coated with a silica (dense) layer as a transparent protective coating having a refractive index n2 of about 1.45 to 550 nm and a variable thickness e3 as follows: for E1: e3 is about 80 nm, for E2 e3 is about 130 nm, for E3, e3 is about 200 nm, for E4 e3 is about 250 nm, and a formulation used for all four examples is prepared. 12.45 ml solution of tetraethoxysilane -TEOS- (40% by weight) and 17.55 ml of aqueous HCI at pH2 are stirred for at least one hour. To 26 ml of this pre-hydrolysed solution of TEOS is added 15 ml of an aqueous solution of solid polymeric pore-forming agents which are BT21 latex beads (Neocryle-about 80 nm diameter) marketed by IMCD France SAS, and 9m1 of HCI at pH2. Each glass of Examples E1 to E4 of this liquid mixture was covered by spin coating at a speed of 750 rpm and an acceleration of 1000 rpm for 30 seconds. After drying for 30 min at 110 ° C. On this dried layer, a liquid composition of variant formulation is covered for examples E1 to E4 as indicated below. A 10.7 g of a solution of tetraethoxysilane -TEOS- + methyltriethoxysilane -MTEOS- at 28 (3) By weight in isopropanol -IPA- (commercial solution of Evonik under the name Xeniosis) is added 89.3 g of IPA so as to obtain a concentration of 33% (3/0 by weight of TEOS + MTEOS The deposition of this mixture is carried out on the cooled dried layer by spin coating at an acceleration of 1000 rpm for 30 s, at a speed of 2000 rpm. 7 g of a solution of tetraethoxysilane -TEOS- + methyltriethoxysilane -MTEOS- at 28 (3/0 by weight in isopropanol -IPA- are added 89.3 g of IPA so as to obtain a concentration of 3% by weight of TEOS + MTEOS The deposition of this mixture is carried out on the cooled dried layer, by spin coating (spinette) at a temperature of 1000 r / s for 30 seconds, at a speed of 2000 rpm E3 10 A 21.4 g of a tetraethoxysilane solution -TEOS- + methyltriethoxysilane -MTEOS- at 28 (3/0 by weight in isopropanol-IPA- are added 78.6 g of IPA so as to obtain a concentration of 6% by weight of TEOS + MTEOS. This mixture is deposited on the cooled dried layer by spin coating at an acceleration of 1000 rpm for 30 seconds, at a speed of 2000 rpm. E4 A 21.4 g A solution of tetraethoxysilane -TEOS- + methyltriethoxysilane -MTEOS- at 28% by weight in isopropanol -IPA- is added 78.6 g of IPA so as to obtain a concentration of 6% by weight of TEOS + MTEOS The deposit of this mixture is carried out on the cooled dried layer, by spin coating (spin coating) at an acceleration of 1000 rpm for 30 s, at a speed of 2000 rpm Then for each example El to E4 is annealed as follows: rise to 100 ° C in 10 min, 100 ° C for 1 h, 100 to 450 ° C in 3 h, 450 ° C for 3 h, then cool. the maximum level at 600 ° C or even beyond by decreasing the duration to less than 15min, even 5min, possibly bending the glass, and / or even possibly an op Quenching Example E1 to E3 was foiled with EVA and a clear, white lacquered glass covering the entire bonding face. The extraction means are the white diffusing enamel of Example 1, on the outer face. The luminances measured at the normal of the examples E1 to E3 are increased with the thickness e3. By comparison, in the absence of the protective silica layer, the guidance is not satisfactory.
[0055] Preferably, a thickness e3 of at least 180 nm and even at least 300 nm or 400 nm is chosen.
[0056] A black, opaque encapsulation primer is deposited on the protective coating of Example E4. The luminance measured at the normal of E4 is satisfactory. By comparison, in the absence of the protective silica layer, the guidance is not satisfactory. Preferably, a thickness e3 of at least 180 nm and even at least 300 nm or 400 nm is chosen. Surprisingly, it is possible to carry out, if necessary, a porous silica gel sol bilayer of at least 600 nm and better 800 nm (and preferably submicron) / sol-gel dense micron silica (of at most 3 μm even of at most 2 μm) without generating cracks. 15 20 25 30 35

权利要求:
Claims (14)
[0001]
REVENDICATIONS1. Luminous glazing (100, 300, 500, 700, 800, 1000) comprising: - a first glass substrate (1) made of mineral glass having a refractive index n1 of less than 1.6 at 550 nm, with first and second main faces (11, 12) and a wafer (13), and in optical contact with the first glass substrate: - a polymeric layer, chosen from at least one of the following elements: - a lamination interlayer (7), made of thermoplastic material associated with a tinted and / or reflective element (1,5, 5 ', 50, 51, 51', 52), and / or - an opaque polymeric encapsulation (90) or a polymeric encapsulation primer (91), in particular opaque, under an opaque polymeric encapsulation, - an optical isolator directly on the first glass substrate and under the polymeric layer, the insulator comprising a porous silica layer (2) with a thickness e2 of at least 400 nm, index of refraction n2 at 550nm of at most 1.35 at 550nm - a light source (4), optically coupled to the first glass substrate, the first glass substrate, said guide glass guiding the light emitted by the source, light extraction means (6) associated with the guide glass, the luminous glazing further comprising a protective coating (3). ), mineral and transparent, directly on the porous silica layer and directly under the polymeric layer.
[0002]
2. Glazing window (100, 300, 500, 700, 800, 1000) according to claim 1 characterized in that the lamination interlayer (7) is tinted and / or laminated with a second tinted glass substrate (1 ', 51 ') made of inorganic or organic glass and / or which has a so-called bonding main surface bonded to the lamination interlayer and carries a tinted film (51') on the bonding face side (11 ') or main face (12 ') opposite to the bonding face.
[0003]
3. Glazing window (100, 300, 500, 700, 800, 1000) according to one of claims 1 or 2 characterized in that the lamination interlayer (7) is laminated with a second glass substrate (1 ', 51). '), mineral or organic glass, with a principal face called bonding bonded to the lamination interlayer, bonding face (11') and / or face opposite to the bonding face coated with a decorative layer and / or masking device (5,5 '), in particular an enamel or a paint or a reflective coating, peripheral and on the optical coupling side, or distributed and even substantially covering the bonding face and / or the opposite face.
[0004]
4. Glazing window (100, 300, 500, 700, 800, 1000) according to one of claims 1 to 3, characterized in that the lamination interlayer (7) is laminated with a second glass substrate, mineral glass or organic, with a principal face called bonding bonded to the lamination interlayer, the bonding face or the opposite main face comprises a diffusing layer and / or said second substrate is diffusing and / or a diffusing element is between the coating protection and lamination interlayer.
[0005]
5. Luminous glazing (200, 400, 600, 900) comprising: a glass substrate, mineral or organic, with a refractive index n1 of less than 1.6 at 550 nm, laminated by a main face called a bonding face to another glass substrate, via a lamination interlayer (7) made of thermoplastic material, the other glass substrate (1 ') is made of mineral glass with a first main face called a lamination face, the other glass substrate (1') is tinted and / or diffusing and / or carrying an element (5 ', 50, 51) tinted and / or diffusing and / or reflecting on the main face opposite to the lamination face, - an optical isolator directly on the lamination face and under the insert, the insulator comprising a porous silica layer (2) with a thickness e2 of at least 400 nm, with a refractive index n2 at 550 nm of at most 1.35 at 550 nm, the other substrate glass maker being called isolated substrate, - a light source (4), optically coupled to said glass substrate, said glass substrate, said guide substrate, guiding the light emitted by the source, light extraction means (6) associated with the guiding substrate, the light glazing further comprising a protective coating (3), mineral and transparent directly on the porous silica layer and directly under the lamination interlayer.
[0006]
6. Glazing window (200, 400, 900) according to claim 5 characterized in that the extraction means (6) are on the side of the lamination, closer to the guiding substrate (1) than the protective coating (3) .
[0007]
7. Luminous glazing (100, 200, 300, 400, 500, 600, 700, 800, 900, 1000) according to one of the preceding claims characterized in that the protective coating (3) comprises a layer of silica with a thickness e3 greater than 50 nm and preferably greater than 100 nm and a refractive index n3 of at least 1.4 to 550 nm.
[0008]
8. Luminous glazing (100, 200, 300, 400, 500, 600, 700, 800, 900, 1000) according to one of the preceding claims, characterized in that the protective coating (3) comprises a layer of silica with a thickness e3 greater than 180 nm and an index of refraction n3 of at least 1.4 to 550 nm.
[0009]
9. Light pane (100, 200, 300, 400, 500, 600, 700, 800, 900, 1000) according to one of the preceding claims characterized in that the porous silica layer (2) is a silica matrix with closed pores in volume, in particular of substantially oval or substantially spherical shape, each of smaller dimension of at least 30 nm and larger dimension of at most 120 nm, preferably between 75 nm and 100 nm, the protective coating comprises a layer with a thickness e3 greater than the largest pore size and preferably submicron.
[0010]
10. Luminous glazing (100, 200, 300, 400, 500, 600, 700, 800, 900, 1000) according to any one of the preceding claims characterized in that the porous silica layer (2) is a ground layer. gel and the protective coating (3) is a sol-gel silica layer.
[0011]
11. Light glazing (300, 700, 800) according to one of the preceding claims characterized in that the porous silica layer (2) partially covers the guide glass (1) or the isolated substrate, thus having a first zone called optical isolation device (24) further comprising the protective coating (3) and the lamination interlayer (7), the first optical isolation zone preferably closer to the light source (4) than the extraction (6) and that a zone (23), said light zone, adjacent and preferably contiguous to the first optical isolation zone comprises the extraction means, in particular formed by a diffusing layer (6).
[0012]
12. Light glazing (300, 700, 800) according to the preceding claim the diffusing layer is a paint, in particular a lacquer, preferably on the second glass substrate (1 ') laminated by the laminating interlayer (7) to the glass of guide (1) or on the laminated laminated interlayer to the second glass substrate (1 ') on the inner side (11).
[0013]
13. Luminous glazing (100, 200, 300, 400, 500, 600, 700, 800, 900, 1000) according to one of the preceding claims characterized in that a diffusing layer (6) is white, especially a paint or an enamel, having a clarity L * of at least 50, preferably which forms part or forms the extraction means opposite the lamination interlayer or the sheet interlayer side in a zone devoid of the optical isolator (2).
[0014]
14. Luminous glazing (100, 200, 300, 400, 500, 600, 700, 800, 900, 1000) according to one of the preceding claims, characterized in that the extraction means (6) are diffusing, in the form of surface texturing, or a diffusing layer, in particular an enamel, a paint, an ink or a diffusing sticker and / or form a light concentrator. Luminous glazing (100, 200, 300, 400, 500, 600, 700, 800, 900, 1000) according to one of the preceding claims, characterized in that the light source (4) is a set of preferably aligned electroluminescent diodes. on a printed circuit board and coupled to the edge of the guide glass or guide substrate. Illuminated glazing unit (1000) according to one of the preceding claims, characterized in that the outer face (12) of the guide glass (1) opposite to the inner face (11) or the outer face opposite to the connecting face is coated at the periphery of the polymeric encapsulation or the encapsulation primer and the polymeric encapsulation. Glazing glass (500) according to any one of the preceding claims, characterized in that it comprises an electrically controllable system with variable optical properties, in particular liquid crystal, optical valve, electrochromic, thermochromic, between the guiding substrate and the coating protection or further from the guide glass (1) than the protective coating (3). Glazing light (100, 200, 300, 400, 500, 600, 700, 800, 900, 1000) according to any one of the preceding claims, characterized in that it forms a vehicle glazing or building glazing. Partition, door, window, shelf or door of refrigerated household or professional equipment, glazing, including closet door, ceiling, railing, wall panel, wall tile, stair step, countertop, showcase, mirror, vehicle glazing incorporating a luminous glazing unit (100, 200, 300, 400, 500, 600, 700, 800, 900, 1000) according to one of the preceding claims. 16. 17. 18. 19.30

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引用文献:

---

公开号 | 申请日 | 公开日 | 申请人 | 专利标题

---

WO2008059171A2|2006-11-14|2008-05-22|Saint-Gobain Glass France|Flat multilayer diffusing structure and manufacturing process thereof|

---

EP2423173A1|2006-11-14|2012-02-29|Saint-Gobain Glass France|Porous layer, method for manufacturing same and uses thereof|

---

WO2012028809A1|2010-08-30|2012-03-08|Saint-Gobain Glass France|Support for organic-light-emitting-diode device, such an organic-light-emitting-diode device and process for manufacturing said device|

---

WO2013167832A1|2012-05-10|2013-11-14|Saint-Gobain Glass France|Illuminating glazing with incorporated deflector|

---

FR2549036B1|1983-07-11|1985-10-18|Saint Gobain Vitrage|SAFETY SHEET GLAZING|

---

FR2751097B1|1996-07-10|1998-09-11|Saint Gobain Vitrage|ELEMENTS WITH VARIABLE OPTICAL / ENERGY PROPERTIES|

---

FR2752570B1|1996-08-22|1998-10-02|Saint Gobain Vitrage|GLAZING WITH VARIABLE OPTICAL AND / OR ENERGY PROPERTIES|

---

FR2779839B1|1998-06-10|2003-06-06|Saint Gobain Vitrage|ELECTRICALLY CONTROLLED SYSTEM WITH VARIABLE OPTICAL PROPERTIES|

---

FR2809496B1|2000-05-23|2002-07-12|Saint Gobain Vitrage|DIFFUSING LAYER|

---

FR2827397B1|2001-07-12|2003-09-19|Saint Gobain|ELECTROCOMMANDABLE DEVICE WITH VARIABLE OPTICAL PROPERTIES OR HOLOGRAPHIC, THERMOTROPIC OR SUSPENDED PARTICLE SYSTEM|

---

ES2191542B1|2001-10-24|2005-02-01|Centro De Investigaciones Energeticas, Medioambientales Y Tecnologicas |PROCEDURE FOR PREPARATION THROUGH THE SOL-GEL TECHNIQUE, FOLLOWING THE POLYMER ROUTE, OF POROUS COATINGS.|

---

AU2003247028A1|2002-08-07|2004-02-25|Koninklijke Philips Electronics N.V.|Display device with light guiding substrate|

---

GB0222765D0|2002-10-02|2002-11-06|Contra Vision Ltd|Glass panels patially printed with ceramic ink layers in substantially exact registration|

---

DE10336283A1|2003-08-08|2005-03-10|Saint Gobain Sekurit D Gmbh|Surface luminous element|

---

JP2007165284A|2005-11-18|2007-06-28|Seiko Instruments Inc|Electroluminescent device and display using same|

---

FR2925483B1|2007-12-20|2010-01-08|Saint Gobain|DECORATIVE GLAZING.|

---

JP5312146B2|2009-03-30|2013-10-09|ユー・ディー・シーアイルランドリミテッド|Light emitting element|

---

FR2964722B1|2010-09-15|2015-11-06|Saint Gobain|MIRROR AND LIGHTING PANEL WITH ELECTROLUMINESCENT DIODES|

---

JP5950505B2|2011-04-08|2016-07-13|キヤノン株式会社|Refractive index distribution structure, manufacturing method thereof, and image display device including refractive index distribution structure|

---

FR2976576B1|2011-06-17|2014-08-08|Saint Gobain|METHOD FOR MANUFACTURING A GLASS SUBSTRATE HAVING PRINTED EMILE PATTERNS|

---

FR2981345A1|2011-10-12|2013-04-19|Saint Gobain|METHOD FOR MANUFACTURING COLORED TRANSPARENT GLASS SHEET|

---

FR2987043A1|2012-02-16|2013-08-23|Peugeot Citroen Automobiles Sa|Laminated glass glazing used for vehicle e.g. motor vehicle, comprises glass sheets that are separated by lamination interlayer and formed by glass plates having a non-uniform thickness surface and defining a non-contact interface|

---

FR2989176B1|2012-04-10|2014-04-25|Peugeot Citroen Automobiles Sa|GLAZING FOR PRODUCING A LIGHT BEAM ACCORDING TO A DIRECTION GIVEN|

---

FR3015926B1|2013-12-31|2017-03-24|Saint-Gobain Glass France|LUMINOUS GLAZING WITH OPTICAL ISOLATOR|US11205926B2|2009-12-22|2021-12-21|View, Inc.|Window antennas for emitting radio frequency signals|

---

FR3015926B1|2013-12-31|2017-03-24|Saint-Gobain Glass France|LUMINOUS GLAZING WITH OPTICAL ISOLATOR|

---

EP3104668B1|2014-02-07|2021-03-24|Toppan Printing Co., Ltd.|Front plate for el element and illumination device|

---

US11114742B2|2014-11-25|2021-09-07|View, Inc.|Window antennas|

---

EP3159608A1|2015-10-23|2017-04-26|AGC Glass Europe|Glass panel with integrated electronic device|

---

WO2017098528A1|2015-12-10|2017-06-15|Saint-Gobain Glass France|Method of installing glass panel|

---

US20190025500A1|2016-01-05|2019-01-24|Corning Incorporated|Laminated light diffusing optical fiber|

---

CN109791338A|2016-08-22|2019-05-21|唯景公司|It is electromagnetically shielded electrochromic|

---

CA3023072A1|2016-05-06|2017-11-09|View, Inc.|Window antennas|

---

US10466392B1|2016-08-26|2019-11-05|Apple Inc.|Systems with textured light-scattering films|

---

DE102016217779A1|2016-09-16|2018-03-22|Audi Ag|Method for operating a motor vehicle|

---

CN106774648B|2016-11-26|2020-04-07|维沃移动通信有限公司|Mobile terminal 3D glass cover plate and ink spraying process method thereof|

---

FR3064941B1|2017-04-07|2019-06-07|Saint-Gobain Glass France|LUMINOUS SHEET GLAZING OF VEHICLE WITH INORGANIC ELECTROLUMINESCENT DIODES AND MANUFACTURE THEREOF.|

---

WO2018215308A1|2017-05-24|2018-11-29|Basf Se|Glazing with luminous coating and method for producing a glazing having a luminous coating|

---

EP3706997A1|2017-11-06|2020-09-16|Saint-Gobain Glass France|Laminated pane with functional element with electrically controllable optical characteristics|

---

CN110446605A|2018-03-06|2019-11-12|法国圣戈班玻璃厂|Composite glass with function element and illumination|

---

FR3084353A1|2018-07-27|2020-01-31|Saint-Gobain Glass France|ENAMELLED SUBSTRATE, LUMINOUS GLASS DEVICE WITH SUCH A SUBSTRATE AND ITS MANUFACTURE.|

---

FR3084355A1|2018-07-27|2020-01-31|Saint-Gobain Glass France|ENAMELLED SUBSTRATE, AUTOMOTIVE LIGHT GLASS DEVICE WITH SUCH SUBSTRATE AND ITS MANUFACTURE.|

---

US20200258478A1|2019-02-11|2020-08-13|GM Global Technology Operations LLC|Programmable glass display|

法律状态:
2015-12-15| PLFP| Fee payment|Year of fee payment: 3 |

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2016-12-16| PLFP| Fee payment|Year of fee payment: 4 |

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2017-12-21| PLFP| Fee payment|Year of fee payment: 5 |

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2018-12-21| PLFP| Fee payment|Year of fee payment: 6 |

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2020-10-16| ST| Notification of lapse|Effective date: 20200910 |

优先权:

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申请号 | 申请日 | 专利标题

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FR1363762A|FR3015926B1|2013-12-31|2013-12-31|LUMINOUS GLAZING WITH OPTICAL ISOLATOR|FR1363762A| FR3015926B1|2013-12-31|2013-12-31|LUMINOUS GLAZING WITH OPTICAL ISOLATOR|

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MX2016008601A| MX2016008601A|2013-12-31|2014-12-23|Luminous glass panel comprising an optical insulator, and production thereof.|

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PCT/FR2014/053529| WO2015101745A1|2013-12-31|2014-12-23|Luminous glass panel comprising an optical insulator, and production thereof|

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EP14831012.1A| EP3089871A1|2013-12-31|2014-12-23|Luminous glass panel comprising an optical insulator, and production thereof|

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JP2016543615A| JP2017504938A|2013-12-31|2014-12-23|Luminescent glass panel containing a photo insulator and its manufacture|

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KR1020167020531A| KR20160105449A|2013-12-31|2014-12-23|Luminous glass panel comprising an optical insulator, and production thereof|

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CN201480002882.3A| CN104884248A|2013-12-31|2014-12-23|Luminous glass panel comprising an optical insulator, and production thereof|

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EA201691350A| EA201691350A1|2013-12-31|2014-12-23|GLOWING GLASS PANEL WITH OPTICAL INSULATOR AND METHOD FOR OBTAINING IT|

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CA2931234A| CA2931234A1|2013-12-31|2014-12-23|Luminous glass panel comprising an optical insulator, and production thereof|

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US15/109,172| US10252494B2|2013-12-31|2014-12-23|Luminous glazing unit with optical isolator and manufacture thereof|